The Korean Society of Surface Science and Engineering

The intermetallic compount formation, growth rections, and growth kinetices as functions of the aging temperaturess, time, and the condition of substarte have invedtigted in the Sn/Cu and Sn/Ni bimetal couples. The η`-phase (Cu6Sn5) and $delta$

The properties of carburization on Fe-Cr alloys at 900-96$0^{circ}C$were investiged. The study on carbide layer which had developed during solid-carburizing was made by use of S.E.M, E.PM.A, and X-ray analyzer. The results obtained were summar

The structural Charactesties and adhesion of chemically vapor deposited TiN film on stain less steels have been investated as functions of deposition temperature, surface roughness of sub state, and types of substrates. The grain zine and the lattice para

It has between investigated that the optimum spaying conditions, such as, spraying distance, fusing temperature and fusing time, ect, in a Ni-cr base self fluxing alloy sprayed on the mild steel substrate by oxygen-acetylenc flame spraying. Sprayed specim

The characteristion of composite electroless Nikel palting on the condition of adding 3kinds ceramic dispersives, Al2O3, Si3O4 and artificial diamond powder were studied. Decreasing solution temperature for composite plating was required to depress the s

The effects of intermetallic compound growt on the sheet resistance and soldreability as functions of the aging time, the temperature, and the conditions of substrates have been investi-gated in the electroplallic compound (mainy Cu6Sn5and Ni3Sn4) and the

A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode,

Pb2+ ino, added in ctching sohing, is electrodeposited on a alumiunm foil for electrolycic condenser to promote its capacitance. In addition, several factoral factors in etching process are varied to examine how they change the capacitance of the condense

Codeposion of inert particles particles in a metallic mateix by electroless plating process involves two phenomena. Firstly, the adsorption of inercles and secondly, the adsorption of inert particles on the cathode. In the present paper the first adsorpti

Mechanism of formation of electroless composite coatings is similar to that of electrodeposited composite coating, but the amount of particles entraped in electroless coating is higher that the one of electrodeposited coatings. The methol of entrapment by

양극산화 피막의 졀정구조에 관한 연구는 1960년대부터 반응 Mechanism의 연구와 병행하여 많은 논란이 되어왔다. 결정구조의 정확한 Model 이 아직까지 확립되어 있지 않은 상태에서, 여러 가지 접근방식으로 연구되고 있는 실정이다. 최근에는 HRTEM, NAS-NMR등의 고성밀 장비의 응용에 의한 결정구조의 분석에 활발히 진행이 되고 있으며, 이론 물리학의 응용 또한 이곳까지 확산되고 있는 상태이다. 본 고에서는 반응 Mechanism을 연구하는

Effects of Na+ ion on zeta potential of SiC and Al2O3 particles suspended in nikel sufate and nickel chloride solutions were investigated. various complexing agents for Ni2+ ion were added to electroless Ni composite bath and the effects of the complexing

The effect of heft treatment on the characteristic properties of insulation layer is studied for two kinds of non-oriented silicon steels, which were insulation-coates with various kinds of inorganic and inorganic-organic complex coating solutions. In add

Insulation coating;Stress relief annealing, Inorganic coating;Inorganic-organic coating;

The rate of electrodeposition Zinc-nickel alloy on to electrolytic ione in sulface solution both under an inter and air atmospherss has studied by use of a rotating disc geometry. The kinetics shows 1st order reaction, and the rate constants are proportio

Mechanism of cobalt deposition was investigated using the potentiodynamic potentiostatic methods in solution of pH 4 and pH6.4 In all experimental conditions, polarization curves showed two regions with different Tafel slopes and the reaction order of cob

Aluminium Oxide was deposited with a C.V.D.-technique on various substrates. The effects of various treating condition such as temperature, time, heat resistance and composition of substrates were investigated in order to understand the relationship of

양극산화 피막의 형성 반응에 대한 연구는 1930년대부터 되어 왔으며, 특히 High Field Conduction에 대한 물리학자들의 관심도는 아주 높아었다. 1960년대 이르러 비정질 구조에 대한 심도 있는 연구가 진행되면서, 여러 가지 이론적으로 풀지 못하는 실험실적 결과들에 대한 제한들이 나오게 되었고, Ionic Migration Process에 대한 Kinetics는 많은 발전을 보게 되었다. 최근까지의 연구결과, Ioinc Conductio

Effects of bath composition on electroless deposition of Ni-W-B from sulphate solution were invesrigated in terms of deposition kinetics, electro resistivity and composition of deposit film. The microstruigated and crystataine structure of the films were

The compositions and microstructures of Pb-Sn alloy electrodeposits were investigated in terms of the electrolysis conditions conditions by using fluoborate bath. The Pb content of alloy deposit decreased with increasing dreasing current density until the

This study seeks to the morphological changes in the oxide skin of the Al-10wt.%si alloy melts. These changes depend on the oxidation time and the temperature of the molten alloy, as well as the effects of adding Mg, Cu and Ni. Thess affects observed by X

The surface modification of a mild and stainless steel by alumina sprayed coating were studied. The effects of surface roughness and bond coating layer on the adhesive strengthy and durability of sprayed specimens were also investiated. The adhesive stren

The Composition and throwing power-of Pb-Sn alloy deposits are investigated in tems of the pulse parameters in pulse plating. Microhardness and intermal srress of alloy deposots are measured. The current efficiency of pulse plating is lower than that of D

The surface morphology and the proferred orientation of the Pb-Sn alloy electrodeposite were investated by the change of electrolysis conditions in pulse current electroplating. The preferred orientation of Pb-phase in alloy deposits was changed in the se

Silicon Nitride whose thickness is about $100AA$by the ellipsometer was successfully formed by the Plasma reaction. Nitrogen Plasma was formed by applying the 200KHz, 500Watt power between the two electroes and nitridation of silicon was carrie

An electroless plating both for normal orientation of HCP-structure of Co-P to the film plane was developed. An ammonical succinate-citrate bath containg MnSo4, NiSO4 was studied Ni was codeposited into the films in order to decrease the saturation magent

The variation of Composition and the microstructure of Zn-Ni alloy electrodespposits were investigated to the electrolysis conditions chloride bath. The codeposition mechanism is of the equilibrium type in the electrolysis condition of the high temperatur

The principe and practice of pulse plating, and prospect in the future on pulse plating are reviewed. Some of the advantages of pulse pulse plating are detailed as compared with DC plating. The advantages of pulse plating are summarized as follows: 1)smoo

$MoS_2$의 상용 고체 윤할제 코팅의 마찰 계수를 하중 100-1000g, Sliding 속도 분당 91-608m 의 범위에서 측정하여 고체윤활체(Sandsttrom 9A)의 하중과 Sliding 속도에 따른 마찰특성을 조사한 결, 하중이 증가함에 따라 또한 Sliding 속도가 증가함에 따른 마찰 계수가 감소함을 나타났다. 또한 고체윤할제 코팅의 전처리인 인삼염 피막처리의 열적특성을 망간계와 아연계 인삼염 피막에 대하여 TGA

The purpose of th this study was to determine an adsorption capaty of cesium by domestic zeolite, clinoptilolite, which has adsorption selectivity and resistence to radiolytic degradation, and to find the operation of column packed natural or Na cinopt

Corrosion behavior of 5-26wt% Ni-Zn electrodeposited alloys was investigated by means of dipping electrochmical polarization measurement and galvanic coupling test. The weight loss and anodic polarization curve of coatings were measured by means of dippin

The high temperature corrosion of Fe-C alloys were studied at I atm SO gas in the temperature range 500~80$0^{circ}C$ by means of a thermogravimetric analysis. The Na2SO4 induced high tempwrature corrosion rate was also measured at atm O2 gas u

To know the growth behavior of Conductive polyaniline file, the anodic oxidation of anilien on a platiunm in aqueous sulfuric acid solution has been studied. Cyclic votammetry and currenttime transisents method used to investigate the anodic oxidation of

The bright nickel electroplatings were carried out the Watt bath containg a solobel saccharin as class I brightner and para substituted benzaldehydes as class II one. Extended Huckel MO calculation was done and polarization was measured to examine between

The anodic oxidation of aniline in aqueous sulfuric acid solution on a platinum was studied. To examine of mechanism of this reaction, the date were obtained during controlled potential electrolysis, aided by computer system. The reaction mechanism was

The principles of the physical vapour deposition processes(PVC); evaporation, sputting, and ion plating are presented and compared with each other with respect to coating properties, deposition rate and process control. The significance of coating sources

최근에 와서 알루미늄소재의 양극산화피막 형성Mechanism에 관한 연구는 응용분야의 폭넓어지면서 많은 연구가 진행되고 있다. 최신분석 장비의 응용의 폭이 넓어짐으로 해서 연구의 깊이도 점차 증가되고 있는 실정이다. 따라서, 선진국 양극산화피막에 관한 연구는 어디까지 왔는가를 조명하므로 해서 그 응용의 기반을 확고히 하기 위해 본 Review를 연재하고자 한다. 본고에서는 가장 기본적인 연구과제와 양극화산화피막의 Morphology에 관한 내용이다.

Electrodeposition of chromium from low concentration chromjum (III) sulfate complexess in aqueous using sodium formate-glycine mixtures as a complexing agent was studied. In the bath formation, it is found that the optimum again temperature and time for e

Electrochemical behaviors od chromium electrodeposition from 0.05M chromium (III) sulface complexes in aqueous solutions using sodium formate-glycine mixtures as a complexing agent were studied. In the cathodic current-potential cures, it is found that th

The nickel0zinc allot depositions have been studjen in ammonium chloridw added chloride baths to fine out the effects of ultrasonic irradiation for the electrodeposition processes. The compositions of deposited alloys, the current efficiencies, corrosion

Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in

양극산화피막의 조성은 현대 장비의 정밀도가 nano 영역까지의 성분 분석이 이루어 짐의로서, 최근에 와서 금속한 진전을 나타내고 있다. 특히 TEM. EDC System을 이용한 Ultramicrotomed 시편의 정밀분석 기술은 이제 한계를 나타내고 있는 것 같다. 본고에서는 반응 Mechanism을 연구하는데 가장 필수적인 분야인 양극산화피막의 조성에 관해 1950 연대 이후 어떻게 연구되고 설명되었는가를 조명하므로 해서, 그 응용의 기반을 확고히

The nickel-zinc alloy depositions have been studied in nickel chloride added chloride baths, to find out the effects of ultrasonic irradiation for the electrodeposition processes. The compositions of deposited alloys, the current efficiencies and the meta

超硬合金과 高速度鋼에 TiC, TiN 그리고 $Al_2O_3$의 耐 마모 코우팅시에 사용되는 CVD와 PVD 기술을 M E Sjostrand와 A G Thelin 등이 본 논문에서 논의하였다. 또한 CVD와 PVD 의 특별한 장점과 응용영역에 대하여도 토의하였다. 수년동안 CVD 기술은 금속질화물, 금속탄화물 그리고 금속산화물 등의 耐 마모 코우팅을 생산하는데 성공적으로 사용되어 왔다. Munster와 Ruppert에서는 1950년대

미국의 정부규격은 국방규격(Military Specification and Standard) 연방규격(Federal Specification Standard)이 있으며 금속표면처리에 관련된 규격인 전기도금규격, 아노다이징, 화성피막처리, 기타 코팅 규격은 40여종으로 되어있다. 이들 규격서와 표준서는 미국내 정부베이소 구매시의 금속표면처리 제품과 때로는 장비의 구입 계약시에 지침이 되고 있다. 전민간의 산업체와 일반 상품의 가공에 생산과 품질관리에 두루

Chromium and Aluminum films were deposited by evaporation technique in $3{ imes}10^{-6}$ mbar vacuum level at the incident angles ranging from $0^{circ};to;60^{circ}$ with various evaporation rates. We measured the sheet resistances

The properties of $Cr_2O_3-Al_2O_3-SiO_2$ composite oxide coatings on steel surface were investigated. The results obtained were as follows: The microhardness of oxide coating layer increased with increasing heat-treatment temperature and

For the purpose of improving the cyclic oxidation resistance of Ni-base superalloy, Inconel 600, aluminide coating methods are studied. The formation rate of aluminide coating layers is measured as a function of time and pack composition to find out the o

지난 3월초 1회용 주사기 메이커인 H사에 기술지도시 정밀한 공차로 제조된 주사기가 그 많은 병원에서 단지 1회 사용후 버리는 것이 무척이나 아까와서 이의 재활용, 도금액 관리에 적용코자 고안하여 특허(?)로 등록하려다가... 여러 회원(Plater)에게 널리 알려 품질 향상과 제조원가 절감의 도금액 관리에 쉽고 간단히 활용하도록 우선 1차로 각종 도금의 전 공정중 산처리액과 수세수 관리에 대하여 기술코져 한다.

최근 10년간 공구의 耐마모 코우팅 분야는 급속한 발전을 하여 왔다. 처음에는 초경 합금 인서트를 TiC로 단층 코우팅하였다. 코우팅 효과를 고려함에 따라 TiC, Ti(C,N), TiN으로 코우팅하게 되었고 또한 $Al_2O_3$ 코우팅도 많이 사용하였다. 처음의 코우팅은 공정작업의 어려움으로 극히 어려웠으나, 밀링작업에 대한 코우팅은 발달하여 왔다. 그림1.은 선반가공과 밀링작업을 하기 위한 초경 합금 인서트를 공구지지대로 지지하

For the purpose of improving the hot corrosion resistance of Ni-base superalloy, Inconel 600, aluminide and chromium-aluminide coatings by pack cementation process were studied. The morphology of these coatings is dependent on the type of process employed

The microhardness and the structural characteristics of the chemically vapor deposited TiN film on the 430 stainless steel substrate have been investigated with various deposition parameters such as the deposition time, the total flow rate, the flow rate

The Zn-Al composite electroplating was studied by using chloride zinc bath containing metal hydroxides $(Zn(OH)_2,;Al(OH)_3))$ and aluminium powder. The size of Al powder codeposited in the beaker bath with Al powder of-400 mesh was under 10

버리는 일회용 주사기와 안약병, 샴프나 음료수병을 함께 사용하여 도금액 공정관리에 활용코자 전호에 이은 기술해설이다. 도금 뿐만아니라 전, 후처리의 모든 공정은 화학과 물리적인 반응이 계속하여 이루어지고 각 공정사이의 수세 공정 또한 액관리가 되어야 할진대, 도금액 관리만이 중요한 액관리인양 도금 공정 이외의 다른 공정은 도외시 하고 있는것이 현실이다. 이에 전공정중 산세, 수세공정 관리법에 이어 탈지공정과 아연도금의 후처리인 크로메이트 처리공정의 액

Various complexing agents were investigated to see the effects on the normal orientation of HCP structure of Co-alloy to the film plane in ammoniacal electroless plating bath. To obtain the optimum condition, several complexing agents were investigated to

In the case of dipping the Ni-Resist cast iron into molten aluminum with iron content, the thickness of intermetallic compound was remarkably increased with increasing iron content. The thickness was shown by following equation in the range of 1-3% iron

The recent literatures on the amorphous plating are reviewed. The methods of the amorphous plating are classified into the electrodeposition and electroless deposition. The structure and properties of the amorphous deposits, and the prospect in the future

급변하는 국내외 환경속에서 국가의 과학기술 발전은 기술정보가 판가름한다고 할 수 있다. 그 기술정보중에서 금속표면처리의 분야는 해외 정보 입수의 어려움, 국내의 번역 및 소개책자의 전무로 정보와 자료를 얻기가 힘들어 선진기술 정보를 알 길이 막혀있다. 관련 기술 정보를 확산, 대중화하는 출판물 등을 통해서 기술 인력의 저변확대와 신기술의 개발에 기대가 클 것은 말할 나위 조차 없다. 다른 산업에 비하여 특히 금속표면처리 관련의 기술 정보 분야는 뒤떨어져

Influences of pH, temperature, and composition of bath on the deposition rate and the magnetic properties were studied for two kinds of electroless Co-P plating bath. The results obtained are as follows. Ammonia alkaline citrate bath was more stable than

Manganese in the Anode slime and the paste-positive material of waste-dry cell was recovered by leaching with the hydrochloric acid solution. The impurities (Zn, Fe, Pb), co-leached with manganese were removed from the leached solution prior to electrolys

이 보고서는 재료의 표면처리에 레이저의 역할이 증가하고 있음을 설명하고 생산현장과 실험실환경에서의 그것의 금속학적인 응용을 조사한다. 변태경화, 표면합금화와 크래딩에 특히 관심을 두었으나, 아직 개발단계에 있는 표면용융, 입자분사와 증착과 같은 기술에 관해서도 언급한다.

The properties of the electroless nickel deposit mainly depends on the pH of the bath, the plating temperature, and the molar ratio of nickel to hypophosphite but they are also affected by its formulation and concentration of complexing and buffering agen

Effects of cathodic overvoltages on the electrodeposition of lead from electrolyte containing lead chloride, ammonium acetate and sodium succinate was investigated at 20$^{circ}C$. The use of organic additives, phenol and gelatin was found effe

A theoretical model was proposed to predict the rate of particles impinging on the negatively biased substrate and the total kinetic energy per unit time. The model takes into an account of kinetic theory based on Maxwell statistics and elementary plasma

SRHS(Self-Regulating High Speed) 크롬도금욕을 사용하여 도금욕온도 10-80$^{circ}C$, 전류밀도 0-400A/$dm^2$의 직류전해도금에서의 전류효율 및 표면광택을 조사하였으며, 동이도금욕 조건에서 펄스 주파수 10-100,000Hz의 펄스전해도금 경우와 비교검토하여 다음과 같은 결론을 얻었다. (1) 20$^{circ}C$의 욕온도의 경우 5-100Hz의 주파

Codeposited of boron nitride(BN) particle dispersed into electroless nickel-phosphours (Ni-P) and nickel-boron(Ni-B) platings were studied for the purpose of developing the wear resistance and lubricity. BN can be codeposited from electroless nickel plati

An electroplating on the lead frame fabricated from domestic copper plate was studied experimentally. In this study, nickel was plated on the thin copper lead frame and silver layer was coated on the nickel film in the cyanide electrolyte. The effect of p

The electroless nickel plating on high alumina ceramics was performed in the bath containing nickel chloride, sodium hypophosphite and mono- or bi-carboxylic acid as a complexing agent in order to examine the empirical rate law as well as the effects of t

There are many plating methods already commercially employed in te surface technology. One of the plating methods is electroless (chemical) plating, which is deposited by auto-catalytic reduction of metallic ion with the reducing agent in the plating bath

The effects of alternating voltage, $Cl^-$ ion and pH on the corrosion of Zn and Zn-Fe alloys have been investigated by using electrochemical techniques in $Ca(OH)_2$ solutions. The passive film $Zn(OH)_2$ was initially fo

Using sodium pyrophoshate as complexing agent, the characteristics and the magnetic properties of the films deposited from electroless cobalt plating bath have been studied. The result obtained are as following; 1. It was found that the optimum bath compo

Titanium was deposited onto AISI-430 stainless steel by chemical vapor deposition from $TiI_4;and;H_2$ gas mixture. Effects of temperature, flow rate of the gas, and $TiI_4$ partial pressure on the deposition rate were thoroughly inv

아무리 제품을 잘 만들어도 최종적인 표면처리가 불량하면 그 제품은 전혀 가치가 없어지는 것은 주지의 사실이다. 현재 우리나라 제품도 무척 좋아져서 선진 제국가의 제품과 어깨를 나란히 할 수 있게 되었다. 86아시안 게임 및 88올림픽등에 우리의 상품을 세계에 떳떳하게 내 놓으려면 이 물건들을 만드는 제조자의 조그만 정성이 필요함은 물론이다. 이런점을 감안하여 여기서는 금속표면을 미려하게하는 도금기술에 대해, 특히 금 도금의 기술문제와 최근 세계의 금 도

The microstructure of zine electrodeposits was investigated by using zinc sulfate solution in still bath. The cathode current efficiency decreased with increasing current density, and decreasing temperature. The preferred orientation of the zinc electrode

A study has been made of preferred orientation, crose sectional microstructure, surface morphology and mechanical properties of copper foils fabricated by electrodeposition on 304 stainless steel plate from copper sulfate baths for high speed plating. The

Lead-tin-copper ternary alloy electrodeposition is conducted onto the inner bore surface of plain bearings as an overlay in order to investigate the effect of slot width, current density and fluoboric acid concentration on the uniformity of overlay. The t

Chemical vapor deposition of $SnO_2$ on Pyrex glass substrate has been investigated using $SnCl_4$ and Oxygen at relatively low temperatures(300-500$^{circ}C$). The critical flow rate, which delineated the surface reaction

설파민산 니켈 용액으로 40~60$^{circ}C$ 온도와 5~25 A/$dm^2$의 전류밀도 범위에서 1mm 두께까지 니켈을 전착시켰다. 1.2V 이상의 음극 과전압 크기에서 핵발생 속도의 증가에 따라 미세한 결정립 크기의 무질서 방위가 나타났고 0.63V에서 미세한 (110) 우선 방위가 나타났으며 그 사이의 크기에서는 강한(100) 우선방위가 형성되었다. (100) 우선방위는 조대한 주상정 조직을 나타냈고,

In the electroless nickel plating bath which contained nickel sulfate, sodium hypophosphite, boric acid and triethanolamine, effect of their concentration on the rate of deposition was tested by gravimetric method and polarization method. The polarization

The microstructure of the zinc electrodeposits was investigated by changing the flow rate of electrolyte in zinc sulfate Bath. The cathode current efficiency increased with increasing flow rate of electrolyte. The preferred orientation of zinc electrodepo

The fluidized bed electrode reactor(FBER) with conducting particles has been made use of the removal of metals from dilute electroplating rinse water. The electrolysis was carried out under the conditions of diaphragm current density with 2~28A/$dm^2

Carburizing of a 12%Cr steel containing 0.6%Si was performed at 950$^{circ}C$ for various times, and the microstructure, hardness and the water characteristics of the carburized chromium steel were examined. The results obtained in this study a

The structure of rapidly solidified Al-Si-based alloys and its relationship to subsequent anodic film growth in near neutral and acid solutions have been investigated. Solidification of the alloys proceeds via pre-dendritic nuclei, associated with rugosit

Zinc was electrodeposited from cyanide solutions at temperature from 20$^{circ}C;to;40^{circ}C$ in the range of current density from 0.5 to 8A/$dm^2$. The preferred orientation changed from (10.3)+(11.0) to (11.0) texture with increa

하루가 다르게 발전하고 있는 최첨단기술인 電子材料의 膜 형성기술중 amorphous silicon(a-Si) 을 電氣鍍金으로 얻는 방법을 소개하였다. 1975년 a-Si이 p-n制御가 가능한 半導體임이 확인된 이후, 큰 면적의 太陽電池, 複寫機用 感光體薄膜, transistor array 등의 응용이 착착 진행되고 있다. 종래의 單結晶실리콘 半導體를 이용한 太陽電池는 가격면에서 비싸 경제성이 적었던 것이 a-Si의 등장으로 小型 計算機등에 까지 a-Si

The surface residual stresses in 1mm thick nickel electrodeposits obtained from four types of nickel sulphamate baths at 40 to 60$^{circ}C$ and 5 to 25 amps./$dm^2$ were measured by a X-ray method. An increase in nickel chloride conc

Hard anodic oxide film was investigated formed on pure aluminium with various temperature (30$^{circ}-60^{circ}C$), current densities (1.5-3.0A/$dm^2$) and concentrations(3-15g/l) of oxalic acid in 0.5M malic acid bath. The resulting

Integral coloring of aluminum and its alloy with the elecrolytic solution of sulfosallicylic acid and sodium hydroxide was investigated in this study. Addition of hydrogen peroxide and potassium permanganate accelerated the anodizing speed and deepened th

Brass was electrodeposited over the range of the current densities from 2 to 8 A/$dm^2$ in cyanide bath at 20 and 40$^{circ}C$. The cathode overpotential increased and the cathode efficiency was decreased respectively with decreasing

The change of the hardness and yield strength depending upon the electrolysis conditions was investigated for Watts and bright nickel electrodeposits. The hardness of Watts nickel electrodeposits decreased with increasing current density in the range of 1

An investigation has been performed on the effects of temperature and Ni addition on the wetting behaviour of Cu on W substrate in hydrogen atmosphere. An sessile drop method was used to measure a wetting angle. The concentration profiles of W, Cu and Ni

석출전위가 낮은 금속들을 저농도용액에서 전기분해하여 회수하는 방법에 대해 아연과 카드뮴을 모델로 삼아 채취방법을 연구하였다. Hull cell과 hyperbolic twin cell에서 시험해서 전류밀도와 효율이 낮기 때문에 기존방법으로는 회수속도가 매우 느린 것을 알 수 있었다. 전해 채취조건을 좋게 하기 위해서는 음극의 표면적을 크게 하고 흔들어 주며, 또 전해액을 강제 순환시켜 물질이동이 잘 되도록 해야만 한다. Rotating tubular be

A study on the improvement of wear resistance of brasses by electroplating and diffusion treatment of tin was carried out. The optimum condition of the treatment obtained was as follows. Plating thickness of tin : 5 - 9 $mu extrm{m}$ Condition

순수 Mo와 Mo-Nb, Mo-Ta($leq$10 at% Nb. Ta)합금을 1,500-2,06$0^{circ}C$ 범위에서 탄소의 고용도를 연구하였다. 특수한 침탄방법으로 C2H2를 시편에 침탄한후 열처리하여 부분적으로 석출하거나 완전석출에 관계없는 화학적 분석방법으로 행하였다. 순수 Mo에서 최대탄소 고용도는 logCCmax = 7.02-9,490/T이다. Nb, Ta를 미량첨가하여 탄소의 최대 고용도는 Arr

The growth rate equation of Fe-Zn alloy layer was represented by x = Kt, and hence the growth of alloy layer was considered to be controlled by diffusion process. The constituent of alloy layer formed on the steel surface was identified to be intermetalli

티오요소류, 폴리에테르류, 염료와 같은 유기화합물이 첨가된 황산동 전기도금욕에서 석출된 구리의 광택, 평활력효과를 무첨가욕과 기존 광택제가 첨가된 도금욕에서와 각각 비교하여 이들 유기첨가제가 구리의 석출상태와 음극분극에 미치는 영향을 Hull cell 실험과 현미경관찰, 전기화학적 측정방법에 의해 고찰하였다. 황산동 전기도금욕에서 thiourea, 2-mercapto-2-imidazoline, 1-acetyl-2-thiourea와 같은 유기 황화합물은

Zinc was electrodeposited at temperature from 20$^{circ}C$ to 60$^{circ}C$ over the ranges of the current density from 2 to 20 A/dm2 in acid chloride bath. The cathode overpotentials increased with increasing current density and decr

The method of trivalent chromium plating has been studied. The relations between the mixing ratio of chromic chloride and DMF, and the corrosion resistance and throwing power of plated chromium have been investigated. As a result, the best result has been

Up to this date, numerous methods of analysis of electroplating solutions are published. Some, however, need lots of works before reaching final results, or require high technique and special instruments, and also some are unaccurate due to unclearne

Electroless plating is the continious formation of metallic coatings from metal ions by che-mical reduction without the use of electrical current. This is, however, more expansive than the conventional electroplating but is often used because of certain a

80% Ni-Permalloy is soft magnetic material with high initial permeability and low magnetic coercive force Hc, and is used to computer memory cores and minirelays of communication e-ngineering. In this paper 80 Permalloy thin film on copper cathode was all

The microstructure of Watts and bright ni-ckel electrodepositss is correlated with pref-erred orientation. The characteristics lamellar structure of bright nickel was atributed to the periodic adsorption of organic additives and related to cyclic fluctuat

The Objective of this study is to analyze structural and operational aspects of the govern-ment, its associations, industries and academic associations related to metal-plating industry, and thereby recommend ways of promotion of subsector, which is yet t

Electroless Ni-plating is often utilized in industries due to its physical and mechanical characteristics in contrast to conventional electroplatings. Thus, electroless Ni-plating will be broadly applicated in many fields. However, The physial and mecha

With a view to manufacturing membranes for separation of gas mixtures, Al foils were anodized in a 2% oxalic-acid electrolyte at 40V and 80V. When anodizing was completed and Barrier layer existed at the extreme back site of the foil, the anodized foil wa

The conditions for the formation of low temperature sulfurized layer and wear characteristics are as follows ; 1. Salt bath KSCN 98%∼K2S 2% showed porous sulfurized layer. 2. Sulfurized layer thickness at 200$^{circ}C$ and 30minutes time was ab

In chemical plating of nickel and chromium on steel, studies on various factors affect-ing the plating operations were carried out. The optimum bath compositions and operat-ing conditions were obtained. The structure and properties of the as deposits or d

The effects of the simultaneous variations of the ratio of feed gases(H2/N2 Flow ratio), feed gas flow rate (H2/N2, total-flow rate) and partial pressures of TiCl4 (PTiCl41) as well as deposition time and cobalt content of the substrate on the deposition

The electrochemical reaction behavior of nickel electrode of the nickel-cadium battery system in potassium hydroxide solution has been studied by cyclic voltammetry, controlled potential electrolysis and X-ray diffraction method. It has been found that t

A study has been made of the interaction parameters of Zn other elements in dilute solutesd solution of molten cadmium alloys over the temperature range of 450 to 570$^{circ}C$. The experi-mental measurementss were made in a touch instant cell

To study the effect of TiC coating on weight change, microhardness, wear and heat - resistance of TiC layer, chemical vapour deposition on the various substrates has been carried out with the gaseous mixture of TiCl4, toluene, and H2 in the temperature ra

The effects of ferrous ion on the properties of bright nickel electrodeposit were exa-mined. Iron exists as ferrous ion (Fe+2) and ferric ion (Fe+3) in the bath, a portion of the former tend to be oxidized to the somewhat harmful ferric ion. Iron was adde

The effects of silicon content on the corrosion rates of Cu-7wt% Al alloys have been investigated by the use of electrochemical methods. The corrosion current densities of the alloys are decreased with the addition of Si up to 2wt%, and the slightly incre

이 작업 표준은 전기도금을 시행하기에 앞서 행하는 탈지작업의 일반적인 기본원칙을 규정한다. 특별한 경우에는 여기서 기술하는 일반적인 기본원칙과 다른 방법으로 탈지작업을 시행해도 무방하다.

니켈 도금의 표면 조직과 두께에 따른 조직의 변화를 투과 전자 현미경을 사용하여 관찰하였다. epitaxial deposit층의 두께는 도금 용액 속에 들어있는 외부 물질에 따라 변화하게 되며, substrate의 결정 방향에 따라 또한 변화한다. (110)면 보다는 (100)면에 도금했을 때 epitaxial deposit 층의 두께가 더 큰 것을 알 수 있었다. non-epitaxial 층으로 변화되는 과정은 hillock의 생성과 계속되는 Twin

The present paper clarified mechanism of quench crack formation in high carbon steel dur-ing quenching, and, in order to prevent the quench crack, proposed two basic guides in alloy design of high carbon tool steel. They are to raise Ms temperature of hig

Electrolytic recovery of gold and silver from diluted solutions has at first been applied nearly 100 years ago. Compared with other recovery techniques electrolytic treatment offers several advantages. But to achieve high space-time yields special constru

The surface appearance of chromium electrodeposit was studied by employing a pulse curr-ent plating in self-regulating high speed (SRHS) bath containing 20 g/$ell$, K2SiF6 7.5 g/$ell$ SrSO4 and 250 g/$ell$ CrO3. As the pul

Section 102(2) (c) of the National Environmental Policy Act of 1969 of the United States requires an environmental assessment of the major federal actions that could significantly a-ffect environmental quality. The review is known as the NEPA assessment p

The crystalline structure and leveling action on the deposit of zinc from the cyanide zinc electroplating bath containing organic additives, such as aldehydes, polymers, amines and condensed product, have been studied by microscope and X-ray diffraction m

The critical voltage of hard coat range of Al alloys (K 186, 43S) at various electrolytes and the effects of voltage, temperature of electrolytes and concentration of sulfric acid were investigated, m the hope that to find the adequate voltage. Two kind o

The mechanical properties of aluminized steel were investigated after the JIS SB 41 plates were dipped in molten aluminum bath. (1) The growth rate of iron-aluminum alloy layer was fast in early stage of alumizing, and then gradually decreased with increa

The effects of various electrodeposition conditions (deposition temperature and cathode current density) on preferred orientation and microhardness of electrodeposited Ni-Sn and Sn-Zn alloys were studied. At deposition temperatures from 25$^{circ}$

Internal stress of electrodeposited metals affect physical and mechanical characteristics of deposits. Internal stress of nickel deposits was reviewed intensively. Important outcomes are as follows. Substrate have an important effect on internal stress of

When anodizing the Al in the acid electrolyte, it is well known that the parallel pores grow continuously perpendicular to the surface. This fact can be used for the manufacturing of the porous membrane, if thc pores pass through the anodized foil. Anodiz